Enantioselective Defluorinative C(sp2)–H Allylation of Acrylamides Enabled by CpxRh(III) Catalysis
In the authors' words
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Main result
Herein, we report a convergent strategy that merges asymmetric alkenyl C(sp2)–H functionalization with defluorinative coupling, enabling the direct, enantioselective synthesis of fluorinated skipped 1,4-dienes from readily available starting materials.
Appeared: Thursday, September 24. Journal of the American Chemical Society. Peer-reviewed journal.
DOI: 10.1021/jacs.6c17644