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Pd-Catalyzed Enantioselective [3+3] Annulation of Vinyldiazos with 2-Iodoanilines Enabled by Sadphos

Dan Zhao, Zhou Luo, Jingyan Luo, Junliang Zhang, Yuanyuan Liu

Peer-reviewed journal

In the authors' words

This journal does not let us republish the full abstract. Here are the two sentences Pipette selected, quoted from it. Read the rest at the publisher.

Main result
Herein, we report the first Pd-catalyzed asymmetric [3+3] annulation of 2-iodoanilines with vinyldiazo acetic esters.

Appeared: Thursday, September 24. Journal of the American Chemical Society. Peer-reviewed journal.

DOI: 10.1021/jacs.6c14159