Pd-Catalyzed Enantioselective [3+3] Annulation of Vinyldiazos with 2-Iodoanilines Enabled by Sadphos
In the authors' words
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Main result
Herein, we report the first Pd-catalyzed asymmetric [3+3] annulation of 2-iodoanilines with vinyldiazo acetic esters.
Appeared: Thursday, September 24. Journal of the American Chemical Society. Peer-reviewed journal.
DOI: 10.1021/jacs.6c14159