Functional Group Transpositional Trimolecular Cross-Coupling via Interrupted Homolytic Substitution

Yuang Cui; Hui Lv; Yizhou Chen; Yang Zhou; Bei‐Bei Zhan; Xiaheng Zhang

doi:10.1021/jacs.6c12532

Chemistry & materialsCatalysis & reactions

Functional Group Transpositional Trimolecular Cross-Coupling via Interrupted Homolytic Substitution

Yuang Cui, Hui Lv, Yizhou Chen, Yang Zhou, Bei‐Bei Zhan, Xiaheng Zhang

Peer-reviewed journalReal-world use

In the authors' words

This journal does not let us republish the full abstract. Here are the two sentences Pipette selected, quoted from it. Read the rest at the publisher.

Main result

Here we introduce a strategy that leverages interrupted homolytic substitution (int-SH2) to enable FGR, specifically redirecting allylamine reactivity toward modular trimolecular cross-coupling via nickel/photoredox dual catalysis.

Read the paper

Appeared: Thursday, September 24. Journal of the American Chemical Society. Peer-reviewed journal.

DOI: 10.1021/jacs.6c12532

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