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Embracing triplet nitrenes for C-to-N replacement of complex bicyclic (hetero)aryl azides

Dong Il Park, Johanna M. Masterson, Yuri Gelato, Jing Ke, Artem V. Tsymbal, Mark D. Levin

Peer-reviewed journal

In the authors' words

This journal does not let us republish the full abstract. Here are the two sentences Pipette selected, quoted from it. Read the rest at the publisher.

Main result
In this work, we report a reaction that productively engages triplet aryl nitrenes for carbon-to-nitrogen replacement on the benzenoid ring of a range of bicyclic heteroarenes, including naphthalenes, anthracene, indoles, benzofurans, benzothiophene, indazoles, and benzisothiazoles.

Appeared: Saturday, September 26. Science. Peer-reviewed journal.

DOI: 10.1126/science.aef3511