Double Boron-Deleting Annulation: Modular Access to Chiral Nonalternant B,N-Helicenes with Enhanced Chiroptical Properties
In the authors' words
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Main result
Herein, we report an unprecedented modular synthesis of nonalternant B,N-embedded helical molecular carbons (HMCs) (BN-HMCs, 12 examples) featuring diaza-pentagon-heptagon pairs via double boron-deleting annulation (dBDA).
Appeared: Saturday, September 26. Journal of the American Chemical Society. Peer-reviewed journal.
DOI: 10.1021/jacs.6c16625