Disentangling Electronic and Lattice Contributions to Transient Absorption in Metal Halide Perovskites: A First-Principles Study of CH3NH3PbBr3
In the authors' words
Abstract Soft lattices combined with strong electron–phonon coupling in metal halide perovskites result in a complex interplay between electronic and lattice degrees of freedom. This interplay complicates the interpretation of time-resolved spectroscopic signals, such as transient absorption spectra. Here, we develop a first-principles approach that combines a nonequilibrium extension of the Bethe-Salpeter equation with ab initio molecular dynamics to resolve the origin of transient absorption. This approach can quantitatively disentangle electronic and thermal lattice contributions across femtosecond-to-picosecond time scales. Exemplified with CH3NH3PbBr3, we find that on the femtosecond scale, both X-ray and optical transient absorption spectra are dominated by electronic contributions: Photoinduced Coulomb screening weakens the effective electron–hole interaction and blueshifts the excitonic resonances, whereas Pauli blocking is negligible in the X-ray region but non-negligible in the optical one. On the picosecond scale, thermal lattice contributions become essential, with distinct mechanisms dominating different spectral regions: Lattice vibrations lead to spectral redistribution in the X-ray transient absorption spectrum, whereas lattice expansion blueshifts the optical transient absorption spectrum.
Appeared: Thursday, September 24. Journal of the American Chemical Society. Peer-reviewed journal.
DOI: 10.1021/jacs.6c14114